Structural analysis of and selective CO<sub>2</sub> adsorption in mixed-ligand hydroxamate-based metal–organic frameworks
Koh Sugamata, Chikaze Takagi, Keiko Awano, Teruyuki Iihama, Mao Minoura
Abstract
Two mixed-ligand metal–organic frameworks using benzene-1,4-dihydroxamic acid and isonicotinic acid were synthesized and fully characterized by single-crystal X-ray crystallography as well as N<sub>2</sub>, H<sub>2</sub>, and CO<sub>2</sub> gas-sorption measurements.
Topics & Concepts
Metal-organic frameworkAdsorptionChemistryLigand (biochemistry)Inorganic chemistryOrganic chemistryBiochemistryReceptorMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsCarbon dioxide utilization in catalysis