Highly selective electrophilic B(9)-amination of <i>o</i>-carborane driven by HOTf and HFIP
Yan Wang, Yan Gao, Wenjing Guo, Qianyi Zhao, Yan‐Na Ma, Xuenian Chen
Abstract
An efficient B(9) electrophilic amination of o -carboranes with azodicarboxylates, promoted by a Brønsted acid and HFIP, was developed.
Topics & Concepts
Electrophilic aminationAminationChemistryElectrophileBrønsted–Lowry acid–base theoryCarboraneCombinatorial chemistryMedicinal chemistryOrganic chemistryCatalysisBoron Compounds in ChemistryOrganoboron and organosilicon chemistryRadiopharmaceutical Chemistry and Applications