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Bistable Elastic Electrochromic Ionic Gels for Energy-Saving Displays

Jiashuang Li, Jingjing Li, Hongbin Li, Chengcheng Wang, Mingfei Sheng, Liping Zhang, Shaohai Fu

2021ACS Applied Materials & Interfaces80 citationsDOI

Abstract

The diversification of electrochromic materials greatly expands the application fields of electrochromic devices. However, highly flexible electrochromic materials remain challenging due to the inherent limitations associated with the existing electrochromic processes. Inspired by the hydrogen bonding effect in the hydrogel structure, a highly elastic and bistable electrochromic ionic gel based on a hydrogen bonding cross-linking network is prepared by solution polymerization having excellent tensile resilience, uniform coloring, reversible switching (≤24.3 s), maximum transmittance change (≥80%), bistability (54 h), reversibility (>500 cycles), and coloration efficiency (≥85.3 cm2·C–1). This method has been used to develop bistable electrochromic displays. The unconventional exploration of the bistable design principle may provide a new idea for the realization of bistable electrochromic devices.

Topics & Concepts

ElectrochromismBistabilityMaterials scienceElectrochromic devicesTransmittanceOptoelectronicsPolymerNanotechnologyIonic bondingElectrodeComposite materialIonOrganic chemistryPhysical chemistryChemistryAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsTransition Metal Oxide Nanomaterials
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