Synthesis and characterization of new Pd(<scp>ii</scp>) and Pt(<scp>ii</scp>) complexes with 3-substituted 1-(2-pyridyl)imidazo[1,5-<i>a</i>]pyridine ligands
Sara Pischedda, Sergio Stoccoro, Antonio Zucca, Giuseppe Sciortino, Fabrizio Ortu, Guy J. Clarkson
Abstract
)Cl] (14) confirmed the spectroscopic and analytical data. Finally DFT studies unveiled the structural reasons behind the inertia of the synthesised compounds toward metalation, identified as the higher angle steric strain in comparison with the analogous bipyridine complexes.
Topics & Concepts
PlatinumChemistryPalladiumArylPyridineStereochemistryMedicinal chemistryCatalysisOrganic chemistryAlkylSynthesis and Reactivity of HeterocyclesMetal complexes synthesis and propertiesSynthesis and Biological Evaluation