An efficient catalytic method for hydrophosphination of heterocumulenes with diethylzinc as precatalyst without a solvent
Bingyi Zhang, Xiaoli Ma, Ben Yan, Congjian Ni, Hailong Yu, Zhi Yang, Herbert W. Roesky
Abstract
The hydrophosphination of heterocumulenes with Ph 2 PH using diethylzinc as precatalyst in neat conditions, which shows excellent catalytic effects. Intermediate is characterized to corroborate the proposed catalytic mechanism.
Topics & Concepts
DiethylzincCatalysisChemistrySolventCatalytic efficiencyOrganic chemistryEnantioselective synthesisOrganophosphorus compounds synthesisSulfur-Based Synthesis TechniquesFerrocene Chemistry and Applications