High Crystalline M<sub>x</sub>Sb<sub>y</sub> (M═Fe, Co, and Ni) Nanocrystals Tuned by Antimony for Boosting Overall Water Splitting Catalysis
Yan Zhang, Jiwen Si, Zihan Chen, Longxin Zhao, Fagui Qiu, Wenqing Li, Wei Zhang, Shiding Miao
Abstract
Abstract Six types of M x Sb y compounds (Fe, Co, and Ni antimonides) are synthesized in form of mono‐dispersed nanocrystallites (NCs) via a hot‐injection metathesis‐reduction. Various contents of Sb atoms are found to drive crystallographic structure and re‐coordination in the M x Sb y materials, leading to rhythmical changes of orthorhombic M 3 Sb→hexagonal MSb→monoclinic (or orthorhombic) MSb 2 . The crystallography is identified as crucial factor in electrocatalysis of water splitting at cathodic and anodic electrodes, respectively. Owning to the in‐plane microstrain distributed along (001) plane, the synthesized Ni 3 Sb NCs are more suitable to catalyzing hydrogen evolution reaction (HER), sharing overpotential (η 10 ) of 93 mV@10 mA cm −2 with Tafel slope of 45 mV dec −1 , and extremely low hydrogen adsorption resistance (0.019 Ω) is obtained. The orthorhombic FeSb 2 NCs featured with larger deprotonation capacity of 13.71 mC V −1 excelled in oxygen evolution reaction (OER) electrolysis, and is confirmed to facilitate minimal deformation of the OOH * . The integrated devices (FeSb 2 ‖Ni 3 Sb) are tested as efficient catalyst for overall water splitting (1.58 V@10 mA cm −2 ) with long stability. Density functional theory (DFT) calculations elucidated the particular coordination of Sb with proper electronegativity (2.05) is able to adjust active sites, relax electronic attraction, and benefit electrochemical reactions.