Metal Ion-Incorporated Lead-Free Perovskites toward Broadband Photodetectors
Junhua Shen, Weiguang Zhu, Zhen Lian, Aming Lin, Su‐Fei Shi, Kun Yang, Mingxin Li, Dong Zhao, Yi‐Yang Sun, Jie Lian
Abstract
Metal halide perovskites have excited tremendous research interests due to their extraordinary photovoltaic and optoelectronic performance. Cs 2 SnI 6 has emerged as a promising lead-free perovskite in advanced optoelectronics due to its high stability, appropriate bandgap, and high absorption coefficient. The performance of two-dimensional (2D) Cs 2 SnI 6 -based photodetectors is limited as compared to lead-based perovskites. Here, we report a simple strategy for incorporating aliovalent metal ions (nickel and zinc) for doping or passivation of perovskites to improve their performance. Aliovalent metal ions are employed to break the inherent dark transition of the 2D Cs 2 SnI 6, greatly increasing photoluminescence by two orders of magnitude than pristine Cs 2 SnI 6 . Density function calculation reveals the n -type doping of nickel ions without introducing any deep trap states. We further demonstrate that the surface passivation of 2D Cs 2 SnI 6 by zinc ions can greatly reduce surface trap/defect density. Aliovalent metal ion-incorporated Cs 2 SnI 6 perovskites exhibit broadband detection, high responsivity (1.6 × 10 3 A W –1, for Ni-incorporated Cs 2 SnI 6 ) and high detectivity (1.56 × 10 13 Jones, for Zn-incorporated Cs 2 SnI 6 ). These results will prompt research on the influence of metal ions in perovskite materials that may afford novel properties for next-generation optoelectronics.