Perfluoroalkyl-functionalization of zirconium-based metal–organic framework nanosheets for photosynthesis of hydrogen peroxide from dioxygen and water
Yoshifumi Kondo, Shiori Mizutani, Yasutaka Kuwahara, Kohsuke Mori, Tohru Sekino, Hiromi Yamashita
Abstract
Hydrophobization of Zr-based MOF nanosheets using perfluoroalkyl carboxylates dramatically promotes photocatalytic hydrogen peroxide production from dioxygen and water.
Topics & Concepts
Hydrogen peroxideZirconiumSurface modificationChemistryMetalPhotosynthesisArtificial photosynthesisInorganic chemistryOrganic chemistryCatalysisBiochemistryPhotocatalysisPhysical chemistryMetal-Organic Frameworks: Synthesis and ApplicationsMesoporous Materials and CatalysisPolyoxometalates: Synthesis and Applications