Manipulating the spin crossover behavior in a series of {FeIII2Fe<sup>II</sup>} complexes
Jia-Tao Chen, Xin-Hua Zhao, Yuan‐Zhu Zhang
Abstract
Three cyanide-bridged {Fe<sub>2</sub>Fe} complexes are reported to exhibit excellent SCO properties which are highly dependent on the compact degree of the π-π stacking, the loss of lattice solvents as well as the electron-donor strength of Tp<sup>R</sup>.
Topics & Concepts
StackingSpin crossoverCrystallographyCyanideLattice (music)ChemistrySeries (stratigraphy)Materials scienceInorganic chemistryPhysicsOrganic chemistryPaleontologyAcousticsBiologyMagnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies