Block Copolymer‐Derived Porous Carbon Fibers Enable High MnO<sub>2</sub> Loading and Fast Charging in Aqueous Zinc‐Ion Battery
Dong Guo, Wenqi Zhao, Fuping Pan, Guoliang Liu
Abstract
Abstract Rechargeable aqueous Zn−MnO 2 batteries are promising for stationary energy storage because of their high energy density, safety, environmental benignity, and low cost. Conventional gravel MnO 2 cathodes have low electrical conductivity, slow ion (de‐)insertion, and poor cycle stability, resulting in poor recharging performance and severe capacity fading. To improve the rechargeability of MnO 2 , strategies have been devised such as depositing micrometer‐thick MnO 2 on carbon cloth and blending nanostructured MnO 2 with additives and binders. The low electrical conductivity of binders and sluggish ion (de‐)insertion in micrometer‐thick MnO 2 , however, still limit the fast‐charging performance. Herein, we have prepared porous carbon fiber (PCF) supported MnO 2 cathodes (PCF@MnO 2 ), comprised of nanometer‐thick MnO 2 uniformly deposited on electrospun block copolymer‐derived PCF that have abundant uniform mesopores. The high electrical conductivity of PCF, fast electrochemical reactions in nanometer‐thick MnO 2, and fast ion transport through porous nonwoven fibers contribute to a high rate capability at high loadings. PCF@MnO 2 , at a MnO 2 loading of 59.1 wt %, achieves a MnO 2 ‐based specific capacity of 326 and 184 mAh g −1 at a current density of 0.1 and 1.0 A g −1 , respectively. Our approach of block copolymer‐based PCF as a support for zinc‐ion cathode inspires future designs of fast‐charging electrodes with other active materials.