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High-efficiency hyperfluorescent white light-emitting diodes based on high-concentration-doped TADF sensitizer matrices <i>via</i> spatial and energy gap effects

Chunbo Duan, Ying Xin, Zicheng Wang, J. Zhang, Chunmiao Han, Hui Xu

2021Chemical Science21 citationsDOIOpen Access PDF

Abstract

, approaching the level of fluorescent tubes. Transient photoluminescence (PL) and electroluminescence (EL) kinetics demonstrate that the spatial separation of TBPe from the TADF sensitizer and TBRb, and the large energy gap between the latter two effectively suppress triplet leakage, in addition to suppressing triplet diffusion in the PhCzSPOTz matrix with anisotropic intermolecular interactions. These results provide a new insight into the exciton allocation process in HF white light-emitting systems.

Topics & Concepts

DopingDiodeLight-emitting diodeMaterials scienceWhite lightOptoelectronicsBand gapOrganic Light-Emitting Diodes ResearchThin-Film Transistor TechnologiesLanthanide and Transition Metal Complexes