Cobalt-Catalyzed Hydrogenation Reactions Enabled by Ligand-Based Storage of Dihydrogen
Sophie W. Anferov, Alexander S. Filatov, John S. Anderson
Abstract
. These results show how ancillary ligands can facilitate efficient catalysis, and furthermore how classic organometallic mechanisms for catalysis can be altered by the secondary coordination sphere.
Topics & Concepts
CatalysisChemistryCoordination sphereLigand (biochemistry)Combinatorial chemistryCobaltMetalationReactivity (psychology)Homogeneous catalysisOrganometallic chemistryPhotochemistryOrganic chemistryMoleculePathologyMedicineReceptorAlternative medicineBiochemistryMagnetism in coordination complexesMetal-Catalyzed Oxygenation MechanismsMetal complexes synthesis and properties