A Multifunctional Porous Uranyl Phosphonate Framework for Cyclic Utilization: Salvages, Uranyl Leaking Prevention, and Fluorescent Sensing
Hongxia Zhao, Chao Qi, Xuewu Yan, Jinyan Ji, Zhifang Chai, Shuao Wang, Tao Zheng
Abstract
The material for managing and monitoring waste made from the waste itself is an excellent example of cyclic utilization, which could reduce issues and be more sustainable. A three-dimensional porous uranyl phosphonate MOF (UPF-105) was synthesized via a hydrothermal method. UPF-105 is stable in aqueous solution with pH in the range of 1–11 and maintains crystallinity below 215 °C. The uncoordinated phosphonate groups in the channels act as functional anchors to selectively capture uranyl ions, with a maximum uranium adsorption capacity of 170.23 mg g–1. The fluorescence of UPF-105 makes it a good candidate for a uranyl ion sensor in uranium-contaminated solutions with concentrations in the range of 5–90 ppm.