Litcius/Paper detail

In-situ measurement of water-vapor in fire environments using a real-time tunable diode laser based system

Shruti Ghanekar, Rajavasanth Rajasegar, Nicholas Traina, Constandinos M. Mitsingas, Richard M. Kesler, Gavin P. Horn, Robin Zevotek, Stephen Kerber, Tonghun Lee

2020Fire Safety Journal12 citationsDOIOpen Access PDF

Abstract

A robust tunable diode laser absorption spectroscopy (TDLAS) based system is developed and deployed to make real-time water-vapor concentration measurements in quasi-controlled live-fire experiments conducted in firefighter training props. This system targets the 1392.5 nm (7181.15 cm−1) water-vapor absorption line while employing a multi-tier detection sensitivity scheme that allows for measurements at multiple locations in fire environment through varying smoke obscuration levels. Temperature-corrected absorbance values are compared to HITRAN simulations to quantify water-vapor concentration. Upon validation in laboratory setting, the impact of firefighter hose stream application on water-vapor concentration is studied. Comparative effects of training structures (metal, concrete and drywall-lined) and fuel-loads (pallet/straw, lightweight furnishings and pallet/straw/oriented-strand-board (OSB)) on water-vapor concentration are characterized. Despite small increase in water-vapor concentration due to suppression, the post-suppression concentrations are found to be comparable or lower than the corresponding maximum pre-suppression concentrations in all scenarios except the metal structure. Irrespective of the structure, highest temperature and water-vapor concentrations are measured with pallet/straw/OSB fuel-load. Under identical fuel-loads, the drywall structure scenarios generate highest water-vapor concentration. Peak water-vapor concentrations are measured post-suppression in typical training structures (near-floor and crawling levels), but prior to suppression in the structure/fuel package combination that simulated a typical residential fire scenario.

Topics & Concepts

Water vaporHITRANMaterials scienceTunable diode laser absorption spectroscopyEnvironmental sciencePalletStrawEnvironmental engineeringMeteorologyOpticsOptoelectronicsAbsorption spectroscopyTunable laserChemistryEngineeringStructural engineeringInorganic chemistryPhysicsWavelengthWind and Air Flow StudiesSpectroscopy and Laser ApplicationsAtmospheric chemistry and aerosols