Four series of lanthanide coordination polymers based on the tetrabromobenzene-1,4-dicarboxylate ligand: structural diversity and multifunctional properties
Suwadee Jiajaroen, Winya Dungkaew, Filip Kielar, Mongkol Sukwattanasinitt, Somboon Sahasithiwat, Hikaru Zenno, Shinya Hayami, Mohammad Azam, Saud I. Al‐Resayes, Kittipong Chainok
Abstract
, respectively, at 50 bar and 298 K with good repeatability of the adsorption-desorption properties. Magnetic studies indicate that the Gd- and Dy-based compounds 1Gd, 1Dy, 3Gd, 3Dy, and 4Gd show simple paramagnetic behaviours, whereas compound 4Dy exhibits weak ferromagnetic interactions.
Topics & Concepts
SBusLanthanideLigand (biochemistry)CrystallographyChemistryCoordination numberIonic radiusIntermolecular forceLanthanide contractionTopology (electrical circuits)IonStereochemistryMetal-organic frameworkMoleculePhysical chemistryOrganic chemistryMathematicsCombinatoricsReceptorBiochemistryAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsLanthanide and Transition Metal ComplexesMagnetism in coordination complexes