Activator Heavy Solid Solution in Rigid Framework: An Effective Strategy Toward Highly Efficient and Thermally Stable Near‐Infrared Emission for Wireless Communication
Shiyu Jia, Zifan Shao, Chuang Zhang, Wenjie Wang, Xinglin Li, Rongfu Zhou, Yayun Zhou, Tingting Deng, Ting Yu, Enhai Song, Enhai Song
Abstract
Abstract Broadband near‐infrared (NIR) phosphors are crucial components of next‐generation NIR lighting sources. However, the design of high‐efficiency and thermally stable NIR phosphors still poses a significant challenge, whose quantum efficiencies (QEs) are directly limited by their absorption efficiency (AE) toward incident light. Here, an efficient and thermally stable NIR emission with AE up to 64.9% and emission keeping of 91.23% at 423 K is demonstrated via Cr 3+ heavy solid solution in rigid framework LiCaGaF 6 :Cr 3+ (LCGFC). Isomorphic LiCaAlF 6 :Cr 3+ also exhibits thermal robustness, while traps in low doping concentration and low QEs. Comparative studies on crystal structure, formation energy, and Helmholtz free energy disclose that Cr 3+ substitution on equivalent and equiradius Ga 3+ site versus radii differential Al 3+ site generates heavier solid solution and sustainable structural rigidity with acquirement of higher AE and better thermal stability. Incorporating LCGFC with a blue InGaN chip, a NIR phosphor‐converted light‐emitting diode is fabricated to realize stable wireless optical communication with good penetrability through biological tissue and some organic products. These findings develop a strategy based on activator heavy solid solutions in a rigid framework to achieve high‐efficiency and thermally stable NIR phosphors but also advance their novel optoelectronic applications.