Self-assembly of Gold Nanorods into a Highly Ordered Sheet via Electrostatic Interactions with Double-stranded DNA
Satoshi Nakamura, Hideyuki Mitomo, Shigeaki Suzuki, Yu Torii, Yu Sekizawa, Yusuke Yonamine, Kuniharu Ijiro
Abstract
Assemblies of cationic gold nanorods (AuNRs) via electrostatic interactions with double-stranded (ds) DNA were investigated in solution and after evaporation as a cast-film. Interestingly, moderately positively charged AuNRs assembled with dsDNA provided a monolayer sheet with an ordered alignment resembling a two-dimensional (2D) smectic structure during solvent evaporation. Assemblies of cationic gold nanorods (AuNRs) via electrostatic interactions with double-stranded (ds) DNA were investigated in solution and after evaporation as a cast-film. Interestingly, moderately positively charged AuNRs assembled with dsDNA provided a monolayer sheet with an ordered alignment resembling a two-dimensional (2D) smectic structure during solvent evaporation.