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Metal‐Based Multihelicenic Architectures

Etienne S. Gauthier, Rafael Rodríguez, Jeanne Crassous

2020Angewandte Chemie18 citationsDOI

Abstract

Abstract The preparation of multihelicenic systems by conventional organic synthesis is a challenging task and under continuous development. In parallel, using complexing units grafted to or incorporated within the helicene core and taking advantage of coordination/organometallic chemistry constitutes a powerful strategy to obtain multihelicenic structures. This Minireview focuses on the state‐of‐the‐art preparation of metal‐based multihelicenic architectures such as coordination‐driven supramolecular assemblies and organometallic architectures. Their properties and their applications are presented.

Topics & Concepts

Supramolecular chemistryNanotechnologyHeliceneCoordination complexGroup 2 organometallic chemistryOrganometallic chemistryMetal-organic frameworkMetalMaterials scienceChemistryCombinatorial chemistryComputer scienceMoleculeOrganic chemistryCatalysisAdsorptionSynthesis and Properties of Aromatic CompoundsLuminescence and Fluorescent Materials
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