Solvatomorphs of (Bu<sub>4</sub>N)<sub>2</sub>[{Ag(N<sub>2</sub>-py)}<sub>2</sub>Mo<sub>8</sub>O<sub>26</sub>]: structure, colouration and phase transition
Pavel A. Abramov⧫, Vladislav Yu. Komarov, Denis A. Pischur, V. S. Sulyaeva, Enrico Benassi, Maxim N. Sokolov⧫
Abstract
(Bu 4 N) 2 [β-{Ag(N 2 -py)} 2 Mo 8 O 26 ] demonstrates monomer/polymer dualism and a colouration phenomenon. The polymeric phase reveals a Ag assisted phase transition. Such complexes can act as precursors for catalytically active materials.
Topics & Concepts
MonomerPolymerCrystallographyPhase transitionPhase (matter)Materials scienceStereochemistryChemistryPhysicsOrganic chemistryThermodynamicsPolyoxometalates: Synthesis and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsCarbon dioxide utilization in catalysis