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Temperature-dependence of the chirality-induced spin selectivity effect—Experiments and theory

Seif Alwan, Subhajit Sarkar, Amos Sharoni, Yonatan Dubi

2023The Journal of Chemical Physics23 citationsDOIOpen Access PDF

Abstract

The temperature-dependence of the chirality-induced spin selectivity (CISS) effect can be used to discriminate between different theoretical proposals for the mechanism of the CISS effect. Here, we briefly review key experimental results and discuss the effect of temperature in different models for the CISS effect. We then focus on the recently suggested spinterface mechanism and describe the different possible effects temperature can have within this model. Finally, we analyze in detail recent experimental results presented in the work of Qian et al. [Nature 606, 902-908 (2022)] and demonstrate that, contrary to the original interpretation by the authors, these data actually indicate that the CISS effect increases with decreasing temperature. Finally, we show how the spinterface model can accurately reproduce these experimental results.

Topics & Concepts

Chirality (physics)Spin (aerodynamics)Experimental dataInterpretation (philosophy)Focus (optics)Mechanism (biology)SelectivityWork (physics)PhysicsChemistryComputer scienceQuantum mechanicsMathematicsThermodynamicsOpticsStatisticsChiral symmetry breakingQuarkCatalysisBiochemistryProgramming languageNambu–Jona-Lasinio modelQuantum and electron transport phenomenaMolecular Junctions and NanostructuresSpectroscopy and Quantum Chemical Studies
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