Kinetic Study of Oxide Growth at High Temperature in Low Carbon Steel
Sixtos Antonio Arreola-Villa, Héctor Javier Vergara–Hernández, Gildardo Solorio-Díaz, Alejandro Pérez-Alvarado, Octavio Vázquez–Gómez, Gerardo Marx Chávez-Campos
Abstract
High-temperature surface oxidation kinetics were determined for low-carbon steel using a Joule heating device on hollow cylindrical specimens. The growth of the oxide layer was measured in situ between 800 and 1050 ∘C under isothermal oxidation conditions and in an air laboratory atmosphere (O2 = 20.3% and humidity = 42%). Through a laser and infrared measuring system, the expansion and temperature were measured continuously. From the data acquired, the oxidation kinetic parameters were obtained at different temperatures with a parabolic-type growth model to estimate the rate of oxide layer generation. The convergence degree of the data fitted with the oxidation model was acceptable and appropriately correlated with the experimental data. Finally, comparisons were made between the estimated kinetic parameters and those reported in the literature, observing that the activation energy values obtained are in the range of the reported values.