Bimodal Evans–Polanyi Relationships in Hydrogen Atom Transfer from C(sp <sup>3</sup> )–H Bonds to the Cumyloxyl Radical. A Combined Time-Resolved Kinetic and Computational Study
Michela Salamone, Marco Galeotti, Eduardo Romero‐Montalvo, Jeffrey A. van Santen, Benjamin D. Groff, James M. Mayer, Gino A. DiLabio, Massimo Bietti
Abstract
)-H donors.
Topics & Concepts
ChemistryBond-dissociation energyKinetic energyHydrogen atomAllylic rearrangementHammett equationReaction rate constantComputational chemistryMarcus theoryGroup (periodic table)Dissociation (chemistry)ThermodynamicsPhysical chemistryKineticsOrganic chemistryCatalysisQuantum mechanicsPhysicsFree Radicals and AntioxidantsMetal-Catalyzed Oxygenation MechanismsRadical Photochemical Reactions