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Photoinduced C(sp <sup>3</sup> )–H functionalization <i>via</i> the photocatalyst-free hydrogen atom transfer pathway

Wei Yi, Yuqi Yang, Xiaoqi Yang, Junkun Yan, Xiao‐Qiang Hu

2025Chemical Communications6 citationsDOI

Abstract

)-H bonds through the photocatalyst-free hydrogen atom transfer (HAT) pathway. We categorize these methodologies based on their specific photoactivation pathways, and provide a detailed discussion on the reaction conditions, substrate scope, and underlying mechanisms.

Topics & Concepts

Surface modificationSubstrate (aquarium)ChemistryCombinatorial chemistryHydrogen atomPhotochemistryChemical modificationNanotechnologyHydrogen bondAtom (system on chip)Materials scienceTransition metalHydrogenBioconjugationChemical bondReaction conditionsOrganic chemistryRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsCyclopropane Reaction Mechanisms
Photoinduced C(sp <sup>3</sup> )–H functionalization <i>via</i> the photocatalyst-free hydrogen atom transfer pathway | Litcius