Kraft Lignin-Derived Microporous Nitrogen-Doped Carbon Adsorbent for Air and Water Purification

Abstract

High Resolution Image Download MS PowerPoint Slide The study presents a streamlined one-step process for producing highly porous, metal-free, N-doped activated carbon (N-AC) for CO 2 capture and herbicide removal from simulated industrially polluted and real environmental systems. N-AC was prepared from kraft lignin─a carbon-rich and abundant byproduct of the pulp industry, using nitric acid as the activator and urea as the N-dopant. The reported carbonization process under a nitrogen atmosphere renders a product with a high yield of 30% even at high temperatures up to 800 °C. N-AC exhibited a substantial high N content (4–5%), the presence of aliphatic and phenolic OH groups, and a notable absence of carboxylic groups, as confirmed by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and Boehm’s titration. Porosity analysis indicated that micropores constituted the majority of the pore structure, with 86% of pores having diameters less than 0.6 nm. According to BET adsorption analysis, the developed porous structure of N-AC boasted a substantial specific surface area of 1000 m 2 g –1 . N-AC proved to be a promising adsorbent for air and water purification. Specifically, N-AC exhibited a strong affinity for CO 2, with an adsorption capacity of 1.4 mmol g –1 at 0.15 bar and 20 °C, and it demonstrated the highest selectivity over N 2 from the simulated flue gas system (27.3 mmol g –1 for 15:85 v/v CO 2 /N 2 at 20 °C) among all previously reported nitrogen-doped AC materials from kraft lignin. Moreover, N-AC displayed excellent reusability and efficient CO 2 release, maintaining an adsorption capacity of 3.1 mmol g –1 (at 1 bar and 25 °C) over 10 consecutive adsorption–desorption cycles, confirming N-AC as a useful material for CO 2 storage and utilization. The unique cationic nature of N-AC enhanced the adsorption of herbicides in neutral and weakly basic environments, which is relevant for real waters. It exhibited an impressive adsorption capacity for the herbicide 2,4-dichlorophenoxyacetic acid (2,4- D ) at 96 ± 6 mg g –1 under pH 6 and 25 °C according to the Langmuir–Freundlich model. Notably, N-AC preserves its high adsorption capacity toward 2,4- D from simulated groundwater and runoff from tomato greenhouse, while performance in real samples from Fyris river in Uppsala, Sweden, causes a decrease of only 4–5%. Owing to the one-step process, high yield, annual abundance of kraft lignin, and use of environmentally friendly activating agents, N-AC has substantial potential for large-scale industrial applications.

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