From BiF<sub>3</sub>to BiF<sub>3</sub>·H<sub>2</sub>O: diverse Bi(<scp>iii</scp>) coordination for structural transformation and birefringence regulation
Xian Liu, Can Yang, Qi Wu, Juan Sun, Fei Liang
Abstract
BiF<sub>3</sub>·H<sub>2</sub>O with unprecedented BiF<sub>9</sub>building blocks was synthesized, which exhibits a near-isotropic Bi<sup>3+</sup>coordination and inert lone pair activity.
Topics & Concepts
BirefringenceTransformation (genetics)CrystallographyMaterials scienceChemistryPhysicsOpticsGeneBiochemistryInorganic Fluorides and Related CompoundsCrystal Structures and PropertiesMetal-Organic Frameworks: Synthesis and Applications