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Conductive Boron Nitride as Promising Catalyst Support for the Oxygen Evolution Reaction

Hui Liu, Xinghua Zhang, Ying‐Xin Li, Xiang Li, Cunku Dong, Deyao Wu, Chengchun Tang, Shulei Chou, Fang Fang, Xi‐Wen Du

2020Advanced Energy Materials62 citationsDOI

Abstract

Abstract Catalyst support with good conductivity and stability is an eternal pursuit in the search for a high‐performance electrocatalyst. Here, an unusual catalyst support, laser‐modified boron nitride with C, O dopants (L‐BN), for the oxygen evolution reaction is reported. L‐BN exhibits unique advantages for electrocatalysis, namely, high corrosion resistance under oxidizing conditions, enhanced electrical conductivity arising from interlayer B–B dipolar interaction, and strong interaction with IrO x catalyst caused by NCN bonds. As an excellent substrate, L‐BN helps to achieve higher activity and stability than its carbon black counterpart.

Topics & Concepts

ElectrocatalystMaterials scienceCatalysisOxidizing agentBoron nitrideDopantChemical engineeringOxygen evolutionConductivityBoronNitrideCorrosionInorganic chemistryElectrochemistryNanotechnologyPhysical chemistryMetallurgyDopingElectrodeChemistryOptoelectronicsOrganic chemistryLayer (electronics)EngineeringElectrocatalysts for Energy ConversionAdvanced Photocatalysis TechniquesMXene and MAX Phase Materials
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