Evolution of microstructures and hydrogen bond interactions within choline amino acid ionic liquid and water mixtures
Jin Chen, Xixi Zeng, Ling Chen
Abstract
endow [Cho][Asp] with stronger cation-anion interactions and less dissociation by water molecules. As a result, the frequency shift degrees and conductivity values of [Cho][Asp]-water mixtures were lower, and the viscosity values were higher than those of [Cho][Lys]-water mixtures. And, [Cho][Lys] could completely dissociate as free hydrated ions at w : IL ≥ 7 : 3, while the free hydrated ions of [Cho][Asp] only occurred when the w : IL ratio reached 8 : 2. These results can ease the experimental effort and improve the application efficiency of [Cho][AA] ILs.
Topics & Concepts
Ionic liquidHydrogen bondAmino acidMicrostructureChemistryCholineLiquid waterIonic bondingChemical engineeringInorganic chemistryOrganic chemistryCrystallographyIonMoleculeBiochemistryThermodynamicsCatalysisPhysicsEngineeringIonic liquids properties and applicationsCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions