Identification of two-dimensional covalent organic frameworks with <b>mcm</b> topology and their application in photocatalytic hydrogen evolution
Peng‐Ju Tian, Xianghao Han, Qiao-Yan Qi, Xin Zhao
Abstract
Three porphyrin-based covalent organic frameworks (COFs) are synthesized. Their structures are exclusively composed of pentagonal pores, giving rise to mcm topology. The COFs exhibit high performance in photocatalytic hydrogen evolution from water.
Topics & Concepts
PhotocatalysisPorphyrinCovalent bondTopology (electrical circuits)Hydrogen bondHydrogenMaterials scienceIdentification (biology)ChemistryNanotechnologyCatalysisPhotochemistryOrganic chemistryMoleculeEngineeringElectrical engineeringBiologyBotanyCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsAdvanced Photocatalysis Techniques