A novel molecularly imprinted quartz crystal microbalance sensor for fenamiphos determination based on boron-sulphur co-doped ultra-thin graphitic carbon nitride-incorporated Cu-MOFs
Şule Yıldırım Akıcı, Ahmet Düzel, Ülkü Melike Alptekin, Sena Bekerecioğlu, İlknur Polat, Necip Atar, Mehmet Lütfi Yola
Abstract
for the FEN molecule, suggesting the successful development of the sensitive molecularly imprinted QCM sensor. The prepared sensitive molecularly imprinted QCM sensor was applied to an apple juice sample with high recovery. Moreover, the high selectivity of the molecularly imprinted QCM sensor was confirmed in the presence of competing agents in the apple juice sample, and the prepared QCM sensor was shown to detect FEN at least 5 times more selectively than the other competing agents. In addition, the proposed sensor was validated in correlation with standard high-end measurements like GC-MS, and there was no significant difference between the results of the proposed sensor and GC-MS method. The low relative standard deviation (RSD) value of 20 independent QCM signals also suggested the high reproducibility of the QCM sensor. Finally, its high repeatability and reusability are presented herein in detail.