Panchromatic Absorption and Oxidation of an Iron(II) Spin Crossover Complex
Johannes Moll, Christoph Förster, Alexandra König, Luca M. Carrella, Manfred Wagner, Martin Panthöfer, Angela Möller, Eva Rentschler, Katja Heinze
Abstract
as well as their charge-transfer (CT) and metal-centered (MC) excited states are probed by variable temperature UV/vis absorption, NMR, EPR, and Mössbauer spectroscopy, magnetic susceptibility measurements at variable temperature as well as quantum chemical calculations.
Topics & Concepts
ChemistryExcited stateLigand (biochemistry)Ligand field theoryAtomic orbitalSpectrochemical seriesElectron paramagnetic resonanceSpin crossoverCrystallographyPyridineAbsorption spectroscopyMetalAbsorption (acoustics)Molecular orbitalPhotochemistryElectronMoleculeAtomic physicsNuclear magnetic resonanceIonOrganic chemistryAcousticsReceptorPhysicsBiochemistryQuantum mechanicsMedicinal chemistryMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms