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Orientation Dependent Interaction and Self‐Assembly of Cubic Magnetic Colloids in a Nematic Liquid Crystal

Devika Venkuzhy Sudhakaran, Ravi Kumar Pujala, Surajit Dhara

2020Advanced Optical Materials20 citationsDOIOpen Access PDF

Abstract

Abstract Spherical microparticles dispersed in nematic liquid crystals have been extensively investigated in the past years. Here, experimental studies are reported on the elastic deformation, colloidal interaction, and self‐assembly of hematite microcubes with homeotropic surface anchoring in a nematic liquid crystal. It is demonstrated that the colloidal interaction and self‐assembly of cubic colloids are orientation dependent. In a notable departure from the conventional microspheres, the microcubes stabilize diverse structures, such as bent chains, branches, kinks, and closed‐loops. The microcubes reorient under external rotating magnetic field, thereby experiencing an elastic torque in the medium, which allows us to measure the magnetic moment through competition between elastic and magnetic torques. The findings envisage that the faceted magnetic colloids in liquid crystals are potential for developing new functional magnetic materials with specific morphologies.

Topics & Concepts

Homeotropic alignmentLiquid crystalMaterials scienceColloidCondensed matter physicsMagnetic momentAnchoringMagnetic nanoparticlesBent molecular geometryMagnetic fieldOrientation (vector space)Chemical physicsSelf-assemblyNanotechnologyComposite materialNanoparticleChemical engineeringGeometryPhysicsOptoelectronicsMathematicsStructural engineeringQuantum mechanicsEngineeringLiquid Crystal Research AdvancementsPickering emulsions and particle stabilizationPlant and animal studies