Cu-catalyzed efficient construction of S (Se)-containing functional organosilicon compounds
Fei Wang, Ying Chen, Weidong Rao, Shusu Shen, Shun‐Yi Wang
Abstract
A Cu-catalyzed cascade reaction of four-membered silacyclobutanes (SCBs) and thiosulfonates to construct S (Se)-containing organosilicon compounds was developed. The protocol shows a wide range of substrate scope, high functional group compatibility and mild reaction conditions. New C-S (Se) and Si-O bonds were constructed in one step.
Topics & Concepts
OrganosiliconCatalysisChemistryCompatibility (geochemistry)Functional groupSubstrate (aquarium)Combinatorial chemistryCascade reactionOrganic chemistryMaterials scienceOceanographyComposite materialPolymerGeologySulfur-Based Synthesis TechniquesOrganoboron and organosilicon chemistryChemical Synthesis and Reactions