Highly Green Fluorescent Carbon Dots from Gallic Acid: A Turn-On Sensor toward Pb<sup>2+</sup> Ions
Hardeep Kaur, Monika Bhattu, Subhendu Chakroborty, Manpreet Kaur Aulakh, Vishal Mutreja, Meenakshi Verma, Karunesh Tiwari, Chandra Chakraborty, Ibrahim A. Darwısh
Abstract
High Resolution Image Download MS PowerPoint Slide Carbon dots (CDs) are emerging novel fluorescent sensing nanomaterials owing to their tunable optical properties, biocompatibility, and eco-friendliness. Herein, we report a facile one-pot hydrothermal route for the synthesis of highly green fluorescent CDs using gallic acid (GA) as a single carbon source in N, N -dimethylformamide (DMF) solvent, which serves as a nitrogen source and reaction medium. The optical properties of the synthesized GA-DMF CDs were systematically characterized by using UV–vis and photoluminescence spectroscopy, revealing strong green fluorescence. Further, to gain insights into their size and structural, elemental, and chemical composition, Fourier transform infrared, dynamic light scattering, high-resolution transmission electron microscopy (HR-TEM), X-ray diffraction, and X-ray photoelectron spectroscopy characterization techniques were performed. HR-TEM analysis confirmed the formation of uniformly spherical GA-DMF CDs with an average particle size of 16 ± 6.1 nm. Notably, the GA-DMF CDs exhibited a highly selective and turn-on fluorescent response to Pb 2+ ions in aqueous solutions, which was attributed to a chelation-enhanced fluorescence mechanism. The detection limit for Pb 2+ ions was determined to be as low as 7.15 × 10 –7 M, with a broad linear detection range of 30–130 μM, underscoring their sensitivity and practical application in water quality monitoring. This study introduces a novel, sustainable approach for synthesizing nitrogen-doped CDs with outstanding optical properties and highlights their unprecedented selectivity toward Pb 2+ ions, advancing the development of efficient and eco-friendly sensing platforms for heavy metal detection.