Litcius/Paper detail

Valence-shell photoelectron circular dichroism of ruthenium(<scp>iii</scp>)-tris-(acetylacetonato) gas-phase enantiomers

Benoît Darquié, Nidal Saleh, S. K. Tokunaga, Monika Srebro‐Hooper, Aurora Ponzi, Jochen Autschbach, Piero Decleva, Gustavo A. García, Jeanne Crassous, Laurent Nahon

2021Physical Chemistry Chemical Physics11 citationsDOIOpen Access PDF

Abstract

propeller-type chirality, are of similar magnitude compared to those on asymmetric-carbon-based chiral organic molecules which constitute the vast majority of species investigated so far, thus suggesting that PECD is a universal mechanism, inherent to any type of chirality.

Topics & Concepts

ChemistryTime-dependent density functional theoryCircular dichroismDensity functional theoryRutheniumValence (chemistry)CrystallographyComputational chemistryOrganic chemistryCatalysisSurface Chemistry and CatalysisMolecular spectroscopy and chiralityAdvanced Chemical Physics Studies