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High and Low Temperature Resistance of Phenyl silicone rubber

Yanhua Huang, Qiuhong Mu, SU Zheng-tao

2021IOP Conference Series Materials Science and Engineering31 citationsDOIOpen Access PDF

Abstract

Abstract Methyl Phenyl and diphenyl silicone rubbers were synthesized from octamethyl cyclotetrasiloxane (D 4 ), methylphenyl cyclosiloxane, octaphenyl cyclotetrasiloxane, etc. Compared with the commercial methylvinyl silicone rubber, the high and low temperature resistances of methyl vinyl silicone rubber were studied in this paper. The results showed that the introduction of phenyl groups can improve the thermal properties of silicone rubber, and the thermal stability of diphenyl silicone rubber is better than that of methyl phenyl silicone rubber. But there is little difference of mechanical properties in high temperature environment for three silicone rubber. DMTA analysis showed that there were still a small amount of crystals in diphenyl silicone rubber, while methylphenyl silicone rubber was amorphous rubber. The mechanical properties at low temperature indicated that the tensile strength of diphenyl silicone rubber was 4.1Mpa higher than that of methylphenyl silicone rubber at -70 °C due to the existence of low-temperature crystallization.

Topics & Concepts

Silicone rubberMaterials scienceNatural rubberThermal stabilityComposite materialUltimate tensile strengthCrystallizationSiliconeGlass transitionDynamic mechanical analysisPolymer chemistryPolymerChemistryOrganic chemistrySilicone and Siloxane ChemistrySynthesis and properties of polymersPolymer Nanocomposites and Properties
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