Synthesis, structures, DFT calculations, and catalytic application in the direct arylation of five-membered heteroarenes with aryl bromides of novel palladium-N-heterocyclic carbene PEPPSI-type complexes
Abd El-Krim Sandeli, Naima Khiri-Meribout, Saida Benzerka, Houssem Boulebd, Nevın Gürbüz, Namık Özdemir, İsmaıl Özdemır
Abstract
A new series of Pd-catalysts was synthesized and fully characterized via spectroscopic methods and the Pd–NHC complexes were evaluated via the direct arylation process.
Topics & Concepts
ChemistryPalladiumCarbeneArylCatalysisCombinatorial chemistryMedicinal chemistryComputational chemistryOrganic chemistryAlkylCatalytic Cross-Coupling ReactionsN-Heterocyclic Carbenes in Organic and Inorganic ChemistryCatalytic C–H Functionalization Methods