Breaking the axiality of pentagonal–bipyramidal dysprosium(<scp>iii</scp>) single-molecule magnets with pyrazolate ligands
Zi‐Han Li, Yuan‐Qi Zhai, Weipeng Chen, Qian‐Cheng Luo, Tian Han, Yan‐Zhen Zheng
Abstract
Ten air-stable dysprosium(<sc>iii</sc>) SMMs with destroyed pentagonal-bipyramidal geometry imposed by axial bidentate-chelating pyrazolate ligands are studied, showing substitutional effect on axial ligands and no effect on equatorial ligands.
Topics & Concepts
DysprosiumPentagonal bipyramidal molecular geometryCrystallographyDenticityChelationChemistryMoleculeTrigonal bipyramidal molecular geometryStereochemistryInorganic chemistryCrystal structureOrganic chemistryMagnetism in coordination complexesLanthanide and Transition Metal ComplexesPorphyrin and Phthalocyanine Chemistry