Catalyst‐Free Synthesis of Thiosulfonates and 3‐Sulfenylindoles from Sodium Sulfinates in Water
Shaoke Li, Zijun Huang, Xin Wang, Hui Yingxiong, Guohao Niu, Ziyan Chen, Zhenlei Zhang
Abstract
This paper presents a green and efficient aqueous-phase method for the synthesis of thiosulfonates, which has the benefits of no need for catalysts or redox reagents and a short reaction time, providing a method with great economic value for synthesizing thiosulfonates. Furthermore, 3-Sulfenylindoles can be easily synthesized using this method, which expands the potential applications of this reaction.
Topics & Concepts
ReagentCatalysisAqueous two-phase systemChemistryAqueous solutionRedoxCombinatorial chemistryOrganic chemistrySulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsCyberloafing and Workplace Behavior