Ligand-to-Copper Charge-Transfer-Enabled C–H Sulfoximination of Arenes
Wanqi Su, Peng Xu, Roland Petzold, Jiyao Yan, Tobias Ritter
Abstract
High Resolution Image Download MS PowerPoint Slide Herein, we report a photoinduced sulfoximine-to-copper charge-transfer-enabled generation of sulfoximinyl radicals directly from NH -sulfoximines for C–H sulfoximination of arenes via radical addition. Through copper-LMCT, N-arylation of NH -sulfoximines was achieved for the first time using arenes of different electronic structures as the aryl donors.
Topics & Concepts
ChemistryCopperArylRadicalCharge (physics)Ligand (biochemistry)PhotochemistryCombinatorial chemistryOrganic chemistryReceptorQuantum mechanicsAlkylPhysicsBiochemistrySynthesis and Catalytic ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques