Health risk assessment and hydrogeochemical modelling of groundwater due to heavy metals contaminants at Basundhara coal mining region, India
Priyajit Samal, Atulya Kumar Mohanty, Somnath Khaoash, Patitapaban Mishra, Kadari Ramaswamy
Abstract
The enrichment of heavy metals and mixing with groundwater resources, which makes a serious threat to human health and the environment. The present study was conducted to determine the enrichment of heavy metals in groundwater, geochemical modelling, and to estimate the probable health risks (non-carcinogenic and carcinogenic) of a coal mining region, in eastern India. The relative abundance of mean heavy metal concentration was in the order of Fe > Zn > Al > Ba > Mn > Sr > Ni > Ag > Cu > Pb > V > Cr > Co > Cd, and are within the WHO standards limits for drinking water values. Groundwater shows pH values as generally acidic to alkaline in nature, while Eh values indicate an oxidising environment. Principal component analysis indicates, metal concentration in the groundwater to be mainly derived from the geogenic sources and in-situ leaching of mine overburden materials. Hydrogeochemical modelling indicates heavy metals are in supersaturation to near neutral state in the groundwater with oxide and carbonate mineral phases. Based on (HPI), and (HEI) values, the majority of groundwater samples are low to moderately contaminated. The health risk assessment model based on hazard quotient (HQ) and hazard index (HI) values show few groundwater samples as crossing the reference limit and have non-carcinogenic health risks for both children and adults. The study identifies the chemical characterisation and potential health risks due to the presence of heavy metals in the groundwater of the coal mining region.