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Reversible Losses in Proton Exchange Membrane Water Electrolysis

Sarah J. Blair, Jacob A. Wrubel, Chance Parrish, Makenzie Parimuha, Jayson Foster, Svitlana Pylypenko, Shaun M Alia, Scott A Mauger, Elliot Padgett

2025Journal of The Electrochemical Society11 citationsDOIOpen Access PDF

Abstract

Lower anode catalyst loadings and higher current densities are essential to lowering the levelized cost of H 2 production via proton exchange membrane water electrolysis (PEMWE). However, these approaches can induce significant durability challenges. Here, we show that cell degradation can include large reversible voltage losses across a variety of conditions, including low loadings and high currents. Although there is limited published discussion of reversible voltage losses in PEMWE, we demonstrate that they are an important consideration in cell efficiency and durability. Understanding the mechanisms of reversible losses and developing mitigation strategies is therefore a key priority for enabling low-cost PEMWE.

Topics & Concepts

ElectrolysisElectrolysis of waterProtonChemical engineeringMaterials scienceChemistryElectrodePhysicsNuclear physicsElectrolyteEngineeringPhysical chemistryFuel Cells and Related MaterialsHybrid Renewable Energy SystemsMembrane-based Ion Separation Techniques
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