A series of dysprosium clusters assembled by a substitution effect-driven out-to-in growth mechanism
Hai‐Ling Wang, Tong Liu, Zhong‐Hong Zhu, Jin-Mei Peng, Hua‐Hong Zou, Fu‐Pei Liang
Abstract
The diacylhydrazone ligands with different substituents were reacted with Dy(NO<sub>3</sub>)<sub>3</sub>·6H<sub>2</sub>O to obtain 16 nuclear (<bold>1</bold>) and 10 nuclear (<bold>2</bold>) and pentanuclear (<bold>3</bold>) dysprosium clusters. Clusters <bold>1–3</bold> are gradually formed through out-to-in growth mechanism.
Topics & Concepts
DysprosiumCrystallographySeries (stratigraphy)ChemistrySubstitution (logic)Mechanism (biology)Inorganic chemistryPhysicsComputer scienceQuantum mechanicsProgramming languagePaleontologyBiologyMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Organic Frameworks: Synthesis and Applications