Discovery of excellent ultraviolet nonlinear optical materials in chlorates and bromates with highly stereochemically active lone pairs
Chun‐Li Hu, Qianqian Chen, Fang Kong, Jiang‐Gao Mao
Abstract
The long-neglected stereochemically active lone pair groups ClO 3 − and BrO 3 − are demonstrated to be important UV NLO functional motifs based on the fact that AClO 3 and ABrO 3 possess high SHG effects and short λ PM and are promising UV NLO materials.
Topics & Concepts
Lone pairNonlinear opticalUltravioletChemistryMaterials sciencePhotochemistryOptoelectronicsNonlinear systemOrganic chemistryPhysicsMoleculeQuantum mechanicsNonlinear Optical Materials ResearchPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies