Diastereoselective formation of homochiral flexible perylene bisimide cyclophanes and their hybrids with fullerenes
Iris Solymosi, Swathi Krishna, Edurne Nuin, Harald Maid, Barbara Scholz, Dirk M. Guldi, M. Eugenia Pérez‐Ojeda, Andreas Hirsch
Abstract
Perylene bisimide (PBI) cyclophanes linked by flexible malonates were functionalized with fullerenes. Modulation of the chemical environment enhances the chiral self-sorting, leading exclusively to the homochiral diastereomeric pair ( M , M )/( P , P ).
Topics & Concepts
PeryleneFullereneChemistryPhotochemistryOrganic chemistryMoleculeFullerene Chemistry and ApplicationsSynthesis and Properties of Aromatic CompoundsMolecular Junctions and Nanostructures