Highly regio- and stereo-selective heterogeneous 1,3-diyne hydrosilylation controlled by a nickel-metalated porous organic polymer
Ying Yang, Yanan Jiang, Zhi-Yi Lin, Jiahao Zeng, Zhikai Liu, Zhuang‐Ping Zhan
Abstract
A porous organic polymer (POL-xantphos) was synthesized and employed as a heterogeneous ligand for nickel catalyzed highly regio- and stereo-selective 1,3-diyne hydrosilylation.
Topics & Concepts
HydrosilylationChemistryXantphosNickelLigand (biochemistry)PolymerPorosityPolymer chemistryOrganic polymerCatalysisChemical engineeringOrganic chemistryPalladiumEngineeringReceptorBiochemistryCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsOrganoboron and organosilicon chemistry