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Spontaneous mirror symmetry breaking and chiral segregation in the achiral ferronematic compound DIO

Neelam Yadav, Yu. P. Panarin, Wanhe Jiang, Georg H. Mehl, J. K. Vij

2023Physical Chemistry Chemical Physics22 citationsDOIOpen Access PDF

Abstract

shows strong polar azimuthal surface interaction energy which stabilizes a homogeneous structure in planar aligned LC cells rubbed parallel and exhibits a twisted structure in cells with antiparallel buffing. The transmission spectra are simulated using Berreman's 4 × 4 matrix method. The observed agreement between the experimental and the simulated spectra quantitatively confirms the presence of twisted structures in antiparallel rubbed cells.

Topics & Concepts

Chirality (physics)Symmetry breakingChiral symmetrySymmetry (geometry)PhysicsSpontaneous symmetry breakingChemical physicsChemistryCondensed matter physicsMaterials scienceCrystallographyQuantum mechanicsExplicit symmetry breakingGeometryMathematicsQuarkLiquid Crystal Research AdvancementsMolecular spectroscopy and chiralityPorphyrin and Phthalocyanine Chemistry
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