Ruthenium(<scp>ii</scp>) complexes with phosphonate-substituted phenanthroline ligands: synthesis, characterization and use in organic photocatalysis
Gleb V. Morozkov, Anton S. Abel, Mikhail A. Filatov, С.Е. Нефедов, Vitaly A. Roznyatovsky, Andrei V. Cheprakov, Alexander Yu. Mitrofanov, Ilia S. Ziankou, Alexei D. Averin, I. P. Beletskaya, Julien Michalak, Christophe Bucher, Laurent Bonneviot, Alla Bessmertnykh‐Lemeune
Abstract
group and the phen core with the 1,4-phenylene linker, singlet oxygen quantum yields significantly increase that favors reactions proceeding through energy transfer (the oxidation of dibutyl sulfide in our case). Thus, both series of Ru(II) complexes prepared in this work are promising for the improvement of known photocatalytic reactions and the development of new transformations.
Topics & Concepts
ChemistryPhotocatalysisSinglet oxygenPhenanthrolineRutheniumPhotochemistryLigand (biochemistry)Electron transferArylAcetonitrileQuantum yieldAlkylCatalysisInorganic chemistryOxygenOrganic chemistryFluorescenceBiochemistryPhysicsReceptorQuantum mechanicsMetal complexes synthesis and propertiesPolyoxometalates: Synthesis and ApplicationsRadical Photochemical Reactions