A calixarene-based coordination cage as an efficient luminescent sensor for Fe<sup>3+</sup>, MnO<sub>4</sub><sup>−</sup>, NB and 2,4-DNP in aqueous medium
Jiamao Zhang, Yue Deng, Shentang Wang, Jun Yang, Shanshan Hu
Abstract
A luminescent coordination cage formulated as {Mg 24 (TC4A) 6 (BTC) 8 (H 2 O) 6 } ( SWU-2 , H 4 TC4A = p-tert -butylthiacalix[4]arene, H 3 BTC = 1,3,5-benzenetricarboxylic acid) was successfully synthesized by the assembly of Mg 4 -TC4A units with BTC ligands.
Topics & Concepts
CalixareneLuminescenceAqueous mediumAqueous solutionCageChemistryCrystallographyTetraSelf-assemblyMaterials scienceInorganic chemistryNanotechnologyPhysical chemistryMoleculeOrganic chemistryMedicinal chemistryOptoelectronicsMathematicsCombinatoricsLanthanide and Transition Metal ComplexesMetal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and Complexes