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Terpolymerization of ethylene, norbornene and dicyclopentadiene catalyzed by modified cyclopentadienyl scandium complexes

Linfeng Wang, Shuqi Dong, Hui Tian, Guangbi Gong, Baoli Wang, Chunji Wu, Dongmei Cui

2023Polymer Chemistry10 citationsDOIOpen Access PDF

Abstract

Terpolymerization of ethylene, norbornene and dicyclopentadiene catalyzed by scandium complexes has been achieved to synthesize corresponding terpolymers. Further transformation results in a huge increase of T g and decrease in the water contact angle.

Topics & Concepts

DicyclopentadieneScandiumNorborneneEthyleneCyclopentadienyl complexCatalysisPolymer chemistryChemistryOrganic chemistryCopolymerPolymerizationPolymerOrganometallic Complex Synthesis and CatalysisCatalytic Cross-Coupling ReactionsCatalytic Alkyne Reactions