Free-Radical-Promoted Dehydrogenative Coupling of Polyfluorinated Alcohol with Quinone, Chromone, and Coumarin
Jingping Liu, Dan Yu, Yong Sheng Yang, Huichao You, Minzhi Sun, Yaxin Wang, Xu Shen, Zhong‐Quan Liu
Abstract
A free-radical-mediated dehydrogenative cross-coupling reaction of polyfluorinated alcohol with quinone, coumarin, and chromone was developed. It provides a sustainable and practical strategy for installation of fluorine atom into organic molecules by using polyfluorinated alcohols.
Topics & Concepts
ChromoneChemistryCoumarinAlcoholQuinoneFluorinePhotochemistryCombinatorial chemistryCoupling (piping)Organic chemistryMechanical engineeringEngineeringCatalytic C–H Functionalization MethodsRadical Photochemical ReactionsOxidative Organic Chemistry Reactions